Chris Young and Cassadee Pope
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Chris Young and Cassadee Pope Surprise the Opry with 'I'm Comin' Over'

Chris Young thrilled the Grand Ole Opry audience when he surprised them with a duet performance of "Think of You" with Cassadee Pope.

During Young's recent trip to the historic Opry, he sang his No. 1 hit off his 2015 record I'm Comin' Over. The audience cheered as Pope appeared onstage to perform the Grammy-nominated tune.

You can watch the full performance from the Grand Ole Opry below.

https://youtu.be/BTlhQCAUes0

Their impromptu performance was full of charisma and chemistry. Although sparks fly during the performance, Young and Pope are just friends both on and off the stage. In fact, Pope just got engaged to her longtime boyfriend and fellow musician Rian Dawson over the weekend.

READ MORE: Watch Dustin Lynch and Cassadee Pope Go Toe to Toe on "Lip Sync Battle"

Young is preparing to hit the road to as support for Jason Aldean's massive They Don't Know Tour. The trek kicks off in April and hits more than 30 stops in the U.S.

Aside from recording and planning a wedding, Pope is also heading out on tour this year. She currently has dates scheduled across the U.S, U.K. and Canada.

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